Four crystalline forms, so-called polymorphs, of ZnCl2 are known, and in each case the Zn2+ ions are tetrahedrally coordinated to four chloride ligands. In aqueous solution, zinc chloride fully dissociated into Zn2+. Illustrative is the preparation of zinc carbonate:
ZnCl2(aq) + Na2CO3(aq) → ZnCO3(s) + 2 NaCl(aq)
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